Physical Transformation AtlasPTA
Phenomenon · phenomenon:ionic-thermoelectric-effect

Ionic thermoelectric effect

A temperature gradient drives differential thermodiffusion of cations and anions in an electrolyte, building an ionic space charge and a thermovoltage of millivolts per kelvin without any electrode redox entropy.

Electrochemistryfirst reported 2011also: ionic Seebeck effect, thermodiffusion of ions

Atlas record: 4 claims reference this phenomenon — 4 established.

Explorerelations · matrix context · routes · sources · cite

conditions: temperature gradient required
4claims10enumerated routes0routes with complete-composition evidence6candidate routes not searched2cited sources

Relations

drives · 1
Temperature gradient—drives→Ionic thermoelectric effectestablished
  • an electrolyte (liquid, gel or polymer) under a temperature difference; ionic Seebeck coefficients of 1–10 mV/K arise from differential thermodiffusion of cations and anions, without electrode redox entropy
produces · 1
Ionic thermoelectric effect—produces→Ionic currentestablished
member of · 1
Ionic thermoelectric effect—member of→Thermodiffusiveestablished
bounded by · 1
Ionic thermoelectric effect—bounded by→Carnot limitestablished

Matrix context

D = disequilibrium row · C = coupling family column. A cell reads the state of the atlas for that pair.

Enumerated routes through this · 10

Cited sources · 2

  1. [1]
    D. Zhao, A. Würger, X. Crispin. Ionic thermoelectric materials and devices (2021)
    Journal of Energy Chemistry 61, 88-103 · doi:10.1016/j.jechem.2021.02.022 · crossref ✓ 2026-09-20 · record
  2. [2]
    M. Bonetti et al.. Huge Seebeck coefficients in nonaqueous electrolytes (2011)
    The Journal of Chemical Physics 134, 114513 · doi:10.1063/1.3561735 · crossref ✓ 2026-09-20 · record

Cite this entity

Physical Transformation Atlas (2026). entity phenomenon:ionic-thermoelectric-effect: Ionic thermoelectric effect. Dataset revision rbfbfcbb70e57 (hash of the canonical data). https://physical-transformation-atlas.wldud5192.workers.dev/phenomenon/ionic-thermoelectric-effect

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