Physical Transformation AtlasPTA
Phenomenon · phenomenon:alkali-metal-thermal-electric-conversion

Alkali-metal thermal-to-electric conversion

Sodium vapour expands across a beta-alumina solid electrolyte that passes ions but not electrons; the electrons take the external circuit. A pressure–temperature difference becomes electricity electrochemically.

Electrochemistryfirst reported 1968also: AMTEC, sodium heat engine

Atlas record: 6 claims reference this phenomenon — 6 demonstrated.

Explorerelations · matrix context · routes · sources · cite

conditions: above ~700 K · liquid
6claims10enumerated routes1routes with complete-composition evidence0candidate routes not searched1cited sources

Relations

drives · 1
Temperature gradient—drives→Alkali-metal thermal-to-electric conversiondemonstrated
  • sodium at 900–1300 K on the hot side of a β″-alumina electrolyte and a condenser at 400–700 K
produces · 1
Alkali-metal thermal-to-electric conversion—produces→Ionic currentdemonstrated
member of · 1
Alkali-metal thermal-to-electric conversion—member of→Electrochemicaldemonstrated
implemented by · 1
Alkali-metal thermal-to-electric conversion—implemented by→AMTEC celldemonstrated
bounded by · 1
Alkali-metal thermal-to-electric conversion—bounded by→Carnot limitdemonstrated
requires · 1
Alkali-metal thermal-to-electric conversion—requires→Sodium β″-aluminademonstrated

Matrix context

D = disequilibrium row · C = coupling family column. A cell reads the state of the atlas for that pair.

Enumerated routes through this · 10

Cited sources · 1

  1. [1]
    T. Cole. Thermoelectric energy conversion with solid electrolytes (1983)
    Science 221, 915–920 · doi:10.1126/science.221.4614.915 · crossref ✓ 2026-09-19 · record

Cite this entity

Physical Transformation Atlas (2026). entity phenomenon:alkali-metal-thermal-electric-conversion: Alkali-metal thermal-to-electric conversion. Dataset revision rbfbfcbb70e57 (hash of the canonical data). https://physical-transformation-atlas.wldud5192.workers.dev/phenomenon/alkali-metal-thermal-electric-conversion

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