Physical Transformation AtlasPTA
Pathway · p-41cb505083 · candidate

Solutocapillary streaming-potential generator (proposed)

Surface energy differenceMarangoni effectFluid flowStreaming potentialIonic currentElectrical work

A surfactant-concentration difference along a free electrolyte surface drives a solutocapillary shear flow past a charged wall, whose streaming potential is the electrical output. Theoretical and numerical only; the route stays a candidate — the nearest physical device (Zhang 2026) runs the Marangoni flow as a co-driver beside capillary transport.

Epistemic state of the route

known constituent relations
5 / 5 established or replicated · weakest constituent replicated
constituent maturity floor
K4 · experimentally observed
search for this exact route
Exact composition search: reviewed 2026-09-21 — partial; No physical demonstration of a surface-energy difference → Marangoni flow → streaming potential → electrical output was found in the OpenAlex protocol runs, the two citation chases or the four Google Scholar forms run by hand on 21/09/2026. The route's literature is the Pini 2015 theoretical proposal and one physical device in which a programmed surface-tension gradient sustains Marangoni microcirculation as a co-driver beside capillary flow in a hydrovoltaic evaporator (Zhang et al. 2026: driver-only-modifies under the parallel-driver rule, since the Marangoni branch's electrical contribution is not isolated). Inconclusive until the Semantic Scholar runs exist and the unread chase hits are read.
recorded pathway
Solutocapillary streaming-potential generator (proposed) · proposed in the literature, not demonstrated — a proposal in the literature, not a demonstration; the route stays a candidate and its search state is unchanged by the proposal
composition maturity
K3 · theoretically quantified
recorded-pathway overlap
none recorded
route-level evidence
2 sources for the complete composition · 6 cited by the constituent steps
boundaries and interfaces
BOUNDARY compatible · no region transition

Explorematrix context · physics checks · performance · steps · route evidence · constituent evidence · cite

Matrix context

D = disequilibrium row · C = coupling family column. A cell reads the state of the atlas for that pair.

D.15 × C.34 · Surface energy difference × Marangonifamily: MarangoniD.15 × C.23 · Surface energy difference × Electrokineticfamily: Electrokinetic

Measured or reported performance

Summary figures only; no datum-level record yet. Each figure below is a reviewed summary, not a single measurement.

notes
Pini, Baier and Dietzel (2015) find concentration-driven (destillocapillary) flows more promising than thermocapillary ones — a finding of the source, not a bound. Zhang et al. 2026 physically demonstrated a graphene-oxide evaporator in which a programmed chemical/surface-tension gradient sustained Marangoni microcirculation alongside capillary flow while the device delivered 25 μA short-circuit current, 0.7 V open-circuit voltage and powered an LED. Route review: driver-only-modifies because capillary and Marangoni transport are simultaneous co-drivers and the electrical contribution of the Marangoni branch was not isolated. Its figures belong to the combined device and are not recorded here.

Typed bounds on this route

Every limit the atlas holds for this route, as constraint records: reached through bounded_by claims on the route's own entities. Hard bounds (an upper bound or a formula) decide the thermodynamic-bound check above; benchmarks, constitutive relations and resource limits are listed and never decisive. No prose limit exists anywhere (pass 42).

  • Onsager–Casimir reciprocity · constitutive-relation · listed, never decisive
    L_ij(B) = ε_i ε_j L_ji(−B): the cross-coefficients of coupled linear transport are equal up to the time-reversal parities ε of the variables and reversal of the magnetic field; L_ij = L_ji is the zero-field, even-parity case

Steps

  1. 01
    surface → kinetic · loss to thermal
    • a gradient of surface tension along a free liquid interface, from composition (solutocapillary) or temperature (thermocapillary)
    liquid
    refs [1] [2]
  2. 02
    Marangoni effect —produces→ Fluid flowestablishedclaim record
    kinetic → kinetic
    refs [1] [2]
  3. 03
    kinetic → electrical · loss to thermal
    • the produced liquid flow passes a charged surface or through a charged channel; the charged boundary is a condition of the step
    • not something the upstream flow provides
    aqueous medium required · bulk flow required · charged surface required
    refs [3] [4]
  4. 04
    electrical → electrical
    refs [4] [5]
  5. 05
    Ionic current —converts into→ Electrical workestablishedclaim record
    electrical → electrical · loss to thermal
    • electrodes exchange the ionic current for an electronic current through the external load
    refs [6]

Evidence for the complete composition · 2

  1. [7]
    C. Pini, T. Baier, M. Dietzel. Energy conversion by surface-tension-driven charge separation (2015)
    Microfluidics and Nanofluidics 19, 721–735 · doi:10.1007/s10404-015-1597-x · record
  2. [8]
    J. Zhang et al.. Chemical-Gradient-Induced Marangoni Flows Boost Solar-Brine Desalination and Enable Concurrent Power Generation (2026)
    Advanced Functional Materials · doi:10.1002/adfm.78354 · record

Evidence for the constituent relations · 6

  1. [1]
    L. E. Scriven, C. V. Sternling. The Marangoni Effects (1960)
    Nature 187, 186-188 · doi:10.1038/187186a0 · crossref ✓ 2026-09-20 · record
  2. [2]
    Q. Dai et al.. Directional interfacial motion of liquids: Fundamentals, evaluations, and manipulation strategies (2021)
    Tribology International 154, 106749 · doi:10.1016/j.triboint.2020.106749 · crossref ✓ 2026-09-20 · record
  3. [3]
    J. Yin, et al.. Generating electricity by moving a droplet of ionic liquid along graphene (2014)
    Nature Nanotechnology 9, 378–383 · doi:10.1038/nnano.2014.56 · crossref ✓ 2026-09-19 · record
  4. [4]
    J. Yang et al.. Electrokinetic microchannel battery by means of electrokinetic and microfluidic phenomena (2003)
    Journal of Micromechanics and Microengineering 13, 963 · doi:10.1088/0960-1317/13/6/320 · crossref ✓ 2026-09-19 · record
  5. [5]
    R. J. Hunter. Zeta Potential in Colloid Science: Principles and Applications (1981)
    Academic Press · doi:10.1016/C2013-0-07389-6 · crossref ✓ 2026-09-19 · record
  6. [6]
    A. J. Bard, L. R. Faulkner. Electrochemical Methods: Fundamentals and Applications (2nd ed.) (2001)
    Wiley · book, no DOI · record

Cite this route

Physical Transformation Atlas (2026). route p-41cb505083: Solutocapillary streaming-potential generator (proposed). Dataset revision rbfbfcbb70e57 (hash of the canonical data). https://physical-transformation-atlas.wldud5192.workers.dev/path/41cb505083

Ids and matrix addresses are stable across revisions; the revision hash identifies the exact canonical files the record was compiled from and is meta.data_hash in every /api export. Reuse terms: see the license field in any export.