Solutocapillary streaming-potential generator (proposed)
Surface energy differenceMarangoni effectFluid flowStreaming potentialIonic currentElectrical work
A surfactant-concentration difference along a free electrolyte surface drives a solutocapillary shear flow past a charged wall, whose streaming potential is the electrical output. Theoretical and numerical only; the route stays a candidate — the nearest physical device (Zhang 2026) runs the Marangoni flow as a co-driver beside capillary transport.
Epistemic state of the route
- known constituent relations
- 5 / 5 established or replicated · weakest constituent replicated
- constituent maturity floor
- K4 · experimentally observed
- search for this exact route
- Exact composition search: reviewed 2026-09-21 — partial; No physical demonstration of a surface-energy difference → Marangoni flow → streaming potential → electrical output was found in the OpenAlex protocol runs, the two citation chases or the four Google Scholar forms run by hand on 21/09/2026. The route's literature is the Pini 2015 theoretical proposal and one physical device in which a programmed surface-tension gradient sustains Marangoni microcirculation as a co-driver beside capillary flow in a hydrovoltaic evaporator (Zhang et al. 2026: driver-only-modifies under the parallel-driver rule, since the Marangoni branch's electrical contribution is not isolated). Inconclusive until the Semantic Scholar runs exist and the unread chase hits are read.
- recorded pathway
- Solutocapillary streaming-potential generator (proposed) · proposed in the literature, not demonstrated — a proposal in the literature, not a demonstration; the route stays a candidate and its search state is unchanged by the proposal
- composition maturity
- K3 · theoretically quantified
- recorded-pathway overlap
- none recorded
- route-level evidence
- 2 sources for the complete composition · 6 cited by the constituent steps
- boundaries and interfaces
- BOUNDARY compatible · no region transition
Explorematrix context · physics checks · performance · steps · route evidence · constituent evidence · cite
Matrix context
D = disequilibrium row · C = coupling family column. A cell reads the state of the atlas for that pair.
D.15 × C.34 · Surface energy difference × Marangonifamily: MarangoniD.15 × C.23 · Surface energy difference × Electrokineticfamily: Electrokinetic
Literature search for this exact composition
No physical demonstration of a surface-energy difference → Marangoni flow → streaming potential → electrical output was found in the OpenAlex protocol runs, the two citation chases or the four Google Scholar forms run by hand on 21/09/2026. The route's literature is the Pini 2015 theoretical proposal and one physical device in which a programmed surface-tension gradient sustains Marangoni microcirculation as a co-driver beside capillary flow in a hydrovoltaic evaporator (Zhang et al. 2026: driver-only-modifies under the parallel-driver rule, since the Marangoni branch's electrical contribution is not isolated). Inconclusive until the Semantic Scholar runs exist and the unread chase hits are read.
- Energy conversion by surface-tension-driven charge separation (2015) · theory only · The same analysis covers destillocapillary (surfactant-concentration-driven) streaming and finds it more promising than thermocapillary drive; theory and numerics only (arXiv 1609.09404 read in full). Recorded as the route's proposed pathway.
- Electro-Marangoni Effect in Thin Liquid Films (2011) · wrong coupling · Drainage → streaming potential → electro-Marangoni surface flow: the streaming potential is upstream of the Marangoni effect, the reverse of the route (abstract).
- Can phoretic motions be treated as interfacial tension gradient driven phenomena? (1981) · wrong coupling · Title: phoretic particle motions (diffusio-/thermophoresis) treated as interfacial-tension-gradient phenomena; particle motion, not a streaming electrical output. Abstract not accessible (Elsevier 1981); not read beyond the title.
- Sustained interfacial powering through self-generated mantle and siphon of a gelling droplet (2026) · wrong coupling · A long-lived solutal Marangoni motor (self-propelled gelling droplet): the output is mechanical self-propulsion, no electrical response (abstract).
- Sedimentation potential in a dilute suspension of ion-adsorbed liquid drops under gravity: Marangoni effects and interfacial charge (2025) · wrong driver · Title: the electrokinetic (sedimentation) potential arises from gravity-driven drop motion, with Marangoni effects as a modifier of drop mobility; the driver is gravity, not a surface-energy difference. Not read beyond the title.
- Chemical-Gradient-Induced Marangoni Flows Boost Solar-Brine Desalination and Enable Concurrent Power Generation (2026) · driver only modifies · Surfaced by the sibling thermal route's Google Scholar runs (21/09/2026). A graphene-oxide evaporator with a programmed longitudinal gradient of oxygen-containing groups: the persistent surface-tension disparity sustains Marangoni microcirculation that co-drives water transport with capillary flow ('a dual-driving transport regime'), while the device delivers 25 μA short-circuit current and 0.7 V open-circuit voltage and series units power an LED. D → M1 is physical, but capillary transport is a simultaneous independent driver and the electrical output is not decomposed into capillary-driven and Marangoni-driven parts (parallel-driver rule). The nearest physical device to this route; recorded as a note on the proposed pathway, its figures kept off the pathway's measurements.
- Circadian humidity fluctuation induced capillary flow for sustainable mobile energy (2022) · wrong driver · Ionic-liquid drops on a nanowire array swell and shrink with the daily humidity, and the surface-tension-regulated cap profile drives an inward/outward capillary flow whose streaming potential is harvested (an LED and an LCD lit). The driver is the humidity fluctuation and the flow is capillary, not a surface-tension gradient; the Gibbs–Marangoni effect is invoked for a detail of the flow (abstract read on OpenAlex).
- Polypyrrole@TiO2 Composite Nanotube System with Enhanced Capillary Fluid and Charge Transfer for High-Current Hydrovoltaic Energy Generation and Seawater Desalination (2024) · driver only modifies · An evaporation-driven hydrovoltaic generator; the Marangoni effect is invoked for salt-film behaviour in the text (Scholar snippet), not as the driver of the streaming output. Not read beyond the snippet.
- Thin liquid film drainage: Ionic vs. non-ionic surfactants (2010) · wrong coupling · Film drainage generates the streaming potential; the surface-tension gradient (Marangoni effect) is a stabilising surface stress in the drainage model, not the driver of the flow — the same physics as the electro-Marangoni papers already recorded (Scholar snippet).
- Onsager relation for electrokinetics at surfactant-covered bubble film (2025) · theory only · A theory of electrokinetics at a surfactant-covered bubble film under pressure-driven flow, in which the Marangoni stress from surfactant accumulation modifies the streaming current; the flow is pressure-driven (Scholar snippet; DOI resolved on OpenAlex).
- In Situ Studies of the Effect of CO2 on the Initial NaCl-Induced Atmospheric Corrosion of Copper (2005) · insufficient information · A corrosion study whose text suggests that a surface-tension gradient in the electrolyte droplet induces Marangoni convection that could give rise to a streaming potential difference; no energy conversion is measured and the passage is known only from Scholar's snippet. Not read.
1032 indexed works reported across the queries, 151 unique retrieved; nobody has read them for a qualifying demonstration. A person can screen this frozen list and promote it to a reviewed record without re-running the query.
- OAdriver-mechanism:1515 reported · 100 retrieved
- OAdriver-mechanism:1515 reported · 50 retrieved
- OAmechanism-pair:1-22 reported · 2 retrieved
- OAwhole-chain0 reported · 0 retrieved
- OAdemonstration-precision0 reported · 0 retrieved
Planned runs NOT run in this bundle (engine unavailable): search:2026-09-20-p-41cb505083/s2-dm1 (semantic-scholar); search:2026-09-20-p-41cb505083/s2-mp12 (semantic-scholar); search:2026-09-20-p-41cb505083/s2-wc (semantic-scholar); search:2026-09-20-p-41cb505083/s2-dp (semantic-scholar).
Protocol route-search-v1: a frozen index run changes only the search state; only a reviewed record can say that a demonstration was or was not found.
Measured or reported performance
Summary figures only; no datum-level record yet. Each figure below is a reviewed summary, not a single measurement.
- notes
- Pini, Baier and Dietzel (2015) find concentration-driven (destillocapillary) flows more promising than thermocapillary ones — a finding of the source, not a bound. Zhang et al. 2026 physically demonstrated a graphene-oxide evaporator in which a programmed chemical/surface-tension gradient sustained Marangoni microcirculation alongside capillary flow while the device delivered 25 μA short-circuit current, 0.7 V open-circuit voltage and powered an LED. Route review: driver-only-modifies because capillary and Marangoni transport are simultaneous co-drivers and the electrical contribution of the Marangoni branch was not isolated. Its figures belong to the combined device and are not recorded here.
Typed bounds on this route
Every limit the atlas holds for this route, as constraint records: reached through bounded_by claims on the route's own entities. Hard bounds (an upper bound or a formula) decide the thermodynamic-bound check above; benchmarks, constitutive relations and resource limits are listed and never decisive. No prose limit exists anywhere (pass 42).
- Onsager–Casimir reciprocity · constitutive-relation · listed, never decisiveL_ij(B) = ε_i ε_j L_ji(−B): the cross-coefficients of coupled linear transport are equal up to the time-reversal parities ε of the variables and reversal of the magnetic field; L_ij = L_ji is the zero-field, even-parity case
Steps
- 01surface → kinetic · loss to thermal
- a gradient of surface tension along a free liquid interface, from composition (solutocapillary) or temperature (thermocapillary)
liquidrefs [1] [2] - 02
- 03kinetic → electrical · loss to thermal
- the produced liquid flow passes a charged surface or through a charged channel; the charged boundary is a condition of the step
- not something the upstream flow provides
aqueous medium required · bulk flow required · charged surface requiredrefs [3] [4] - 04electrical → electricalrefs [4] [5]
- 05electrical → electrical · loss to thermal
- electrodes exchange the ionic current for an electronic current through the external load
refs [6]
Evidence for the complete composition · 2
- [7]C. Pini, T. Baier, M. Dietzel. Energy conversion by surface-tension-driven charge separation (2015)
- [8]J. Zhang et al.. Chemical-Gradient-Induced Marangoni Flows Boost Solar-Brine Desalination and Enable Concurrent Power Generation (2026)
Evidence for the constituent relations · 6
- [1]L. E. Scriven, C. V. Sternling. The Marangoni Effects (1960)
- [2]Q. Dai et al.. Directional interfacial motion of liquids: Fundamentals, evaluations, and manipulation strategies (2021)
- [3]J. Yin, et al.. Generating electricity by moving a droplet of ionic liquid along graphene (2014)
- [4]J. Yang et al.. Electrokinetic microchannel battery by means of electrokinetic and microfluidic phenomena (2003)
- [5]R. J. Hunter. Zeta Potential in Colloid Science: Principles and Applications (1981)
- [6]A. J. Bard, L. R. Faulkner. Electrochemical Methods: Fundamentals and Applications (2nd ed.) (2001)
Cite this route
Physical Transformation Atlas (2026). route p-41cb505083: Solutocapillary streaming-potential generator (proposed). Dataset revision rbfbfcbb70e57 (hash of the canonical data). https://physical-transformation-atlas.wldud5192.workers.dev/path/41cb505083
Ids and matrix addresses are stable across revisions; the revision hash identifies the exact canonical files the record was compiled from and is meta.data_hash in every /api export. Reuse terms: see the license field in any export.